We report a comprehensive temperature-dependent investigation of the 1:2 ordered triple perovskite system ${\mathrm{Sr}}_3\mathrm{Ca}{\mathrm{Ru}}_2{\mathrm{O}}_9$. It crystallizes in the monoclinic structure with space group $P{2}_1/c$, consisting of corner-sharing $\mathrm{Ca}{\mathrm{O}}_6$ and $\mathrm{Ru}{\mathrm{O}}_6$ octahedra. Using dc magnetization and neutron diffraction measurements, we show that this system undergoes successive magnetic transitions at ∼190 and ∼160 K. From the analysis of the temperature-dependent neutron diffraction and dielectric data, we demonstrate two distinguishing features of the ${\mathrm{Sr}}_3\mathrm{Ca}{\mathrm{Ru}}_2{\mathrm{O}}_9$ system: (i) magnetoelastic coupling associated with the two magnetic transitions, as revealed by a change in the unit cell volume, direct Ru-Ru distance, and bond angles and (ii) magnetodielectric coupling, as revealed by the anomalies across the two magnetic transitions. The present results would add significantly to the current understanding of the triple perovskites with incipient spin-orbit coupling.

• Received 19 July 2023
• Revised 3 January 2024
• Accepted 19 January 2024

DOI:https://doi.org/10.1103/PhysRevMaterials.8.024405