${\mathrm{SrTiO}}_3$ is one of the most studied transition metal oxides. Recently, a breakthrough was achieved with the fabrication of freestanding ${\mathrm{SrTiO}}_3$ ultrathin films down to the monolayer limit. However, the many-body effects on the quasiparticle and optical properties of monolayer ${\mathrm{SrTiO}}_3$ remain unexplored. Using state-of-the-art many-body perturbation theory in the GW approximation combined with the Bethe-Salpeter equation, we study the quasiparticle band structure, optical, and excitonic properties of monolayer ${\mathrm{SrTiO}}_3$. We show that quasiparticle corrections significantly alter the band-structure topology; however, the widely used diagonal ${\mathrm{G}}_0{\mathrm{W}}_0$ approach yields unphysical band dispersions. The correct band dispersions are restored only by taking into account the off-diagonal elements of the self-energy. The optical properties are studied both in the optical limit and for finite momenta by computing the electron energy loss spectra. We find that the imaginary part of two-dimensional polarizability at the long wavelength limit is dominated by three strongly bound excitonic peaks and the direct optical gap is associated to a bright exciton state with a large binding energy of 0.93 eV. We discuss the character of the excitonic peaks via the contributing interband transitions and reveal that the lowest bound excitonic state becomes dark for finite momenta along $\mathrm{\Gamma }-M$, while the other two excitonic peaks disperse to higher energies and eventually merge for momenta close to $M$.

• Received 20 June 2023
• Revised 7 November 2023
• Accepted 8 January 2024

DOI:https://doi.org/10.1103/PhysRevMaterials.8.024001