Simple Model for Dynamic Heterogeneity in Glass-Forming Liquids

Rajib K. Pandit and Horacio E. Castillo
Phys. Rev. Lett. 131, 218202 – Published 22 November 2023

Abstract

Liquids near the glass transition exhibit dynamical heterogeneity, i.e., local relaxation rates fluctuate strongly over space and time. Here, we introduce a simple continuum model that allows for quantitative predictions for the correlators describing these fluctuations. We find remarkable agreement of the model predictions for the dynamic susceptibility χ4(t) with numerical results for a binary hard-sphere liquid and for a Kob-Andersen Lennard-Jones mixture. Under this model, the lifetime τex of the heterogeneities has little effect on the position t=t4τα of the peak of χ4(t), but it controls the decay of χ4(t) after the peak, and we show how to estimate it from this decay.

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  • Received 27 December 2022
  • Revised 4 June 2023
  • Accepted 24 October 2023

DOI:https://doi.org/10.1103/PhysRevLett.131.218202

© 2023 American Physical Society

Physics Subject Headings (PhySH)

Polymers & Soft Matter

Authors & Affiliations

Rajib K. Pandit* and Horacio E. Castillo

  • Department of Physics and Astronomy and Nanoscale and Quantum Phenomena Institute, Ohio University, Athens, Ohio 45701, USA

  • *Present address: Exact Sciences, Redwood City, California 94063, USA.
  • castillh@ohio.edu

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Issue

Vol. 131, Iss. 21 — 24 November 2023

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